What is the limiting reactant if 0.5 g Al is reacted with 0.5 g CuCl2?
What is the theoretical yield of copper produced by this reaction?

Answer :

Taking into account the reaction stoichiometry ,CuCl₂ is the limiting reagent and the theoretical yield of copper produced is 0.2363 grams.

Reaction stoichiometry

In first place, the balanced reaction is:

2 Al + 3 CuCl₂ → 3 Cu + 2 AlCl₃

By reaction stoichiometry (that is, the relationship between the amount of reagents and products in a chemical reaction), the following amounts of moles of each compound participate in the reaction:

  • Al: 2 moles
  • CuCl₂: 3 moles
  • Cu: 3 moles
  • AlCl₃: 2 moles

The molar mass of the compounds is:

  • Al: 27 g/mole
  • CuCl₂: 134.44 g/mole
  • Cu: 63.54 g/mole
  • AlCl₃: 133.35 g/mole

Then, by reaction stoichiometry, the following mass quantities of each compound participate in the reaction:

  • Al: 2 moles ×27 g/mole= 54 grams
  • CuCl₂: 3 moles ×134.44 g/mole= 403.32 grams
  • Cu: 3 moles ×63.54 g/mole= 190.62 grams
  • AlCl₃: 2 moles ×133.35 g/mole= 266.7 grams

Limiting reagent

The limiting reagent is one that is consumed first in its entirety, determining the amount of product in the reaction. When the limiting reagent is finished, the chemical reaction will stop.

Limiting reagent in this case

To determine the limiting reagent, it is possible to use a simple rule of three as follows: if by stoichiometry 54 grams of Al reacts with 403.32 grams of CuCl₂, 0.5 grams of Al reacts with how much mass of CuCl₂?

mass of CuCl₂= (0.5 grams of Al× 403.32 grams of CuCl₂)÷ 54 grams of Al

mass of CuCl₂= 3.734 grams

But 3.734 grams of CuCl₂ are not available, 0.5 grams are available. Since you have less mass than you need to react with 0.5 grams of Al, CuCl₂ will be the limiting reagent.

Definition of theoretical yield

The theoretical yield is the amount of product acquired through the complete conversion of all reagents in the final product, that is, it is the maximum amount of product that could be formed from the given amounts of reagents.

Theoretical yield of copper

Considering the limiting reagent, the following rule of three can be applied: if by reaction stoichiometry 403.32 grams of CuCl₂ form 190.62 grams of Cu, 0.5 grams of CuCl₂ form how much mass of Cu?

mass of Cu= (0.5 grams of CuCl₂× 190.62 grams of Cu)÷ 403.32 grams of CuCl₂

mass of Cu= 0.2363 grams

Then, the theoretical yield of copper produced is 0.2363 grams.

Summary

In summary, you obtain:

  • CuCl₂ is the limiting reagent.
  • the theoretical yield of copper produced is 0.2363 grams.

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